Interactive comment on “Effect of atmospheric organic complexation on iron-bearing dust solubility” by R. Paris and K. V. Desboeufs
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lines 14-15 “ligand playing on dust iron solubility. . .” Suggested change: “ligand promoting dust iron dissolution. . .” Introduction, 3182, line 17 Remove “the” from “ promote the iron” Introduction, 3182, line 22 Replace “are” with “were” in “compounds are often” Introduction, 3182, lines 27-28 Rearrange sentence for clarity Suggested change: “The aim of this paper is to test the effect of previously identified atmospheric iron binding ligands on the solubility of iron from mineral dust,. . .” Introduction, 3183, line 5 Remove “really” Material and method, 3183, line 9 Replace “Material and method” with “Materials and Methods” Material and method, 3184, line 1 Make “Leaching solution” plural as several leaching solutions were prepared and tested. Material and method, 3184, line 8 Replace “was” with “were” in “solutions was prepared” Material and method, 3184, line 15 Replace “no” with “none of the” in “no studied organic”
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Interactive comment on “Effect of atmospheric organic complexation on iron-bearing dust solubility” by R. Paris and K. V. Desboeufs
We thank Ryan Sullivan for his comment. We are aware to the need to precise the possibility to mixing between dust and organic compounds. The knowledge of this mixing is presented in the introduction of our previous paper Paris et al. (Atmos. Envir., 2011). We know of course his publications and the proposed papers, and some of them are cited in Paris et al. (2011). We had thought to save this ...
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This paper focuses on the solubilization of Fe in dust resulting from the complexation of short chain (2-5) monoand di-carboxylic acids, as well as HULIS. The authors determine that small dicarboxylic acids increase the solubility of Fe, while monoprotic acids have little-to-no effect. The authors also report that this solubilization effect decreases as the carbon chain on the organic acid incr...
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Recent studies reported that the effect of organic complexation may be a potentially important process to be considered by models estimating atmospheric iron flux to the ocean. In this study, we investigated this process effect by a series of dissolution experiments on iron-bearing dust in the presence or the absence of various organic compounds (acetate, formate, oxalate, malonate, succinate, ...
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